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(A) Possible mechanisms of NO x photocatalytic purification ; (B) calculated reaction pathway and structures of initial states, transitional states, and final states for NO photooxidation by on CN and Au@CN ; (C) design diagram for localized excess electrons that decrease the reaction activation energies and increase the photocatalysis efficiency ; (D) DFT calculated adsorption energy and bond length of several major intermediate adsorption products (upward for CN and downward for Sr intercalated CN), all lengths are given in Å ; (E) detailed mechanism of photocatalytic NO oxidation on -OH intercalated BiOI ; (F) diagram of the reduction of the surface by NO and e− ; (G) proposed schematic diagram for the separation and transfer of photogenerated carriers and the photocatalytic process over the insulator–semiconductor heterojunction .
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