Spin-phonon coupling in two-dimensional magnetic materials

Special Topic: Two-dimensional Materials and Devices

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Table 1

Single-crystal synthesis for van der Waals magnetic materials (The type of magnets is divided based on the experimental or theoretical results. The priority concerning the classification is given to the experimental methodologies.)

Type of magnets	Crystal	Transport agent/reaction	Temperature (°C)	Ref.
Ferromagnets	Cr₂Ge₂Te₆	Te self-flux	700	[55]
	Cr₂Si₂Te₆	Te self-flux	500	[56]
	Fe₃GeTe₂	I₂	750–700	[57]
	VTe₂	I₂	900–810	[58]
	VSe₂	I₂	820–720	[58]
	VS₂	I₂	900–850	[59]
	MnSe₂	ICl₃	600–540	[59]
	CrI₃	Auto transport	630–550 650–350	[60] [61]
	CrBr₃	Auto transport	750–200 →750–650	[33]
	GdI₂	Auto transport	827	[62]
	VI₃	Auto transport	650–550	[63]
	VS₂	I₂	900–850	[64]
	InP₃	Auto transport	1200	[65]
	GaSe	Auto transport	990–850	[66]
	GaS	I₂	850–750	[67]
	α-MnO₂	KOH	650	[68]
Antiferromagnets	FePS₃	I₂	650–600	[41]
	FePSe₃	I₂	650–600	[41]
	MnPS₃	I₂	650–600	[41]
	MnPSe₃	I₂	650–600	[41]
	NiPS₃	I₂	650–600	[41]
	NiPSe₃	KCl-AlCl₃ flux	−	[69]
	CuCrP₂Se₆	SeCl₄	650–600	[70]
	AgCrP₂S₆	I₂	800–750	[71]
	AgVP₂S₆	Auto transport	600	[72]
	CrSe₂	Oxidation of K_xCrSe₂(X~1) with iodine in acetonitrile		[73]
	CrTe₂	Oxidation of KCrTe₂ with iodine in acetonitrile		[74]
	CrTe₃	KCl-AlCl₃ flux	450–425	[75]
	Ni₃Cr₂P₂S₉	Auto transport	800	[76]
	MnBi₂Te₄	I₂	590	[77]
	MnBi₂Se₄	I₂	800–700	[78]
	CrCl₃	Auto transport	720–600	[79]
	FeCl₂	AlCl₃	350–250	[64]
	FeBr₂	Ar	500	[80]
	FeI₂	I₂	550	[81]
	MnBr₂	Br₂+Mn in ether	Room temperature
	CoCl₂	AlCl₃	400–300	[64]
	CoBr₂	AlBr₃	345–245	[64]
	NiCl₂	AlCl₃	350–300	[64]
	VCl₂	I₂	350–400	[82]
	VBr₂	I₂	350–400	[82]
	VI₂	I₂	580–520	[64]
	FeCl₃	Cl₂	593→575–588	[83]
	FeBr₃	Br₂	150–200	[84]
	CrOCl	Cl₂	940–840	[64]
	FeOCl	I₂	400–380	[85]
	VOCl	Auto transport	1030–980	[86]
	CrSBr	Br₂	700–900→900–850	[87]
	MnCl₂	AlCl₃	400–350	[64]
	VCl₃	Cl₂	300–250	[64]
	VBr₃	Auto transport	480	[88]
	AFeCl₄ (A = organic cation)	Self-assemble in solution	Room temperature	[89,90]
	AMnCl₄ (A = organic cation)	Self-assemble in solution	Room temperature	[91]
Multiferroics	CuCrP₂S₆	Auto transport	650–600	[70]
	CuCl₂	AlCl₃	450–350	[64]
	CuBr₂	CuO + HBr solution	Room temperature	[92]
	NiBr₂	AlBr₃	345–245	[64]
	NiI₂	I₂	750–700	[93]
	CoI₂	I₂	500–425	[93]
	MnI₂	I₂	590–420	[94]
	SnO	SnCl₂·2H₂O + NaOH hydrothermal	180	[95]
	GeS	I₂	863–788	[96]
	GeSe	I₂	570–450	[97]
	SnS	I₂	950–850	[98]
	SnSe	Auto transport	790–740	[99]
	GaTeCl	Auto transport	260–270	[100]
	CrN	Cr-Ga-Na	850	[101]
	CrB₂	Al	1550	[102]
	ACuCl₄ (A = organic cation)	Self-assemble in solution	Room temperature	[49–51]
	ACrCl₄ (A = organic cation)	Self-assemble in solution	Room temperature	[52,53]
Proximate Kitaev quantum spinliquid	α-RuCl₃	Cl₂	550	[103]
Half metals	MnF₃	F₂	500	[104]
	MnSSe	I₂	945–850	[64]
	TiCl₃	AlCl₃	300–250	[64]
Spin-Peierls	TiOCl	HCl,TiCl₃	650–800→520–600	[105]
Spin-Peierls	TiOBr	Br₂	650–550	[106]

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