Table 2
Technical characteristics of commonly used commercial thermal storage materials [78,80–83]
Thermal storage materials | Working temperature range (°C) | Density (kg/m3) | Specific heat (kJ/(kg K)) | Thermal conductivity (W/(m K)) | Material cost ($/kg) | Advantages | Limitations | |
Sensible thermal | Water | 20‒80 | 1000 | 4.2 | 0.60 | 0.005 | Economical, easy access, environmentally friendly, stable | Low thermal storage density, narrow range of heating source, large heating loss |
Heat transfer oil | −40‒300 | 800‒900 | 1.5‒2.0 | 0.15‒0.30 | 1.2‒10 | High heat transfer efficiency, easy-to-control temperature, non-corrosive | High price, flammable, easy to decompose | |
Rock | 100‒1000 | 1500‒2800 | 0.9‒1.1 | 0.85‒3.50 | 0.02‒0.3 | Economical, good thermal stability | Low thermal efficiency, need a heat transfer medium, poor cycle stability, high heating loss | |
Concrete | 200‒400 | 2000‒2500 | 0.8‒1.0 | 1.0‒2.0 | 1.2‒10 | Wide range of usage temperatures, high strength | High cost, need a heat transfer medium | |
Latent thermal | Ice | <0 | 917 | 2.1 | 2.2 | 0.05 | Economical, easy access, environmentally friendly, strong stability | Volume change is relatively large, low thermal storage density |
Molten salt | 300‒850 | 1800‒2100 | 1.5‒1.8 | 0.60‒0.08 | 0.5‒3.0 | Good heat transfer, high heating storage density | Solidifies easily, corrosive, toxic | |
Hydrous salt | 30‒80 | 1100‒1500 | 1.5‒2.0 | 0.50‒0.6 | 0.2‒1.5 | High thermal conductivity, little change in phase transition volume, low cost | Supercooling phenomenon, corrosion, decomposition | |
Paraffin | 20‒40 | 800‒950 | 2.1‒2.9 | 0.20‒0.30 | 1.0‒3.0 | High latent heating, stable chemical properties | Low efficiency, poor thermal conductivity, large volume change, flammable | |
Polyethylene glycol | 15‒45 | 1000‒1300 | 2.1‒3.1 | 0.10‒0.20 | 1.0‒3.0 | High latent heating, compatible with other materials, recyclable, stable chemical properties | Low efficiency, low thermal conductivity, large volume change, flammable |
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