Metallic glacial glass | National Science Open (NSO)

Special Topic: Glasses—Materials and Physics

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Table 1

Summary on the origin of primary exothermic peaks on the calorimetry curve. T_o, T_p and T_e represent the onset, peak and end temperatures of the primary exo, respectively. Amorphous thin-film, quasicrystals, liquids and glasses are represented by a, q, l and g; l_1’ and l_2’ stand for phase-separated liquids; l₁ and l₂ denote phase-changed liquids

Compositions	Procedures	References
a-to-q
Al₅₅Si₂₅Mn₂₀	Annealed at 600 K (0.92T_o) for 15–46 h Annealed at 730 K (T_e) for 5 s	[60,61]
Al₇₅Cu₁₅V₁₀	Annealed at 630 K (0.875T_x) for 2–52 h at 620 K (0.86T_x) for 11 h at 655–725 K (0.91–1.0T_o) for 6000–60,000 s	[60] [62,63]
Al_82.6Mn_17.4	Annealed at 573 K (T_o) for 1200 s	[51]
Au₇₅Cu₂₅	Annealed at 723 K for 300 s	[64]
Pd_58.8U_20.6Si_20.6	Annealed at 763 K (T_o) for 6000 s Annealed at 766 K (T_o) for 900–4800 s	[67,68] [69]
Pd₆₀U₂₀Si₂₀	Annealed at 713 K (0.95T_o) for 12,000 s Annealed at 795 K (T_o) for 70 s Heated to 585 K (T_e)	[70–73]
Al₈₃Mn₁₇	Heated to 680 K (T_e)	[59]
Al₈₄Mn₁₆	Irradiation	[65]
Al₇₂Mn₂₂Si₆	Thin film deposition with a substrate temperature of 318, 423 or 503 K	[66]
l-to-q
Al₉₀Fe₅Ce₅	Cooling the melt	[156]
Al₅₈Cu₃₄Fe₈	Cooling the melt	[157]
Al₆₀Cu₃₄Fe₆	Cooling the melt	[158,157]
Al₆₅Cu₂₅Co₁₀	Cooling the melt	[158]
Mg₆₉Zn₂₇Yb₄	Cooling the melt	[87]
Zr_39.5Ti_39.5Ni₂₁	Cooling the melt	[80]
Zr_41.5Ti_41.5Ni₁₇	Cooling the melt	[159,160]
Zr₆₀Ti₂₀Ni₂₀	Heated to 700 K (T_p)	[88]
Zr₆₅Cu₁₅Ni₁₀Pd₁₀	Heated to 713 K (T_p)	[89]
Zr₆₅Cu_17.5Al_7.5Pd₁₀	Heated to 728 K (T_p)	[89]
Zr₆₅Cu_7.5Al_7.5Ni₁₀Pd₁₀	Heated to 723 K (T_p)	[89]
Ti₄₀Hf₄₀Ni₂₀	Heated to 773 K (T_e)	[161]
Zr₅₇Ti₈Nb_2.5Cu_13.9Ni_11.1Al_7.5	Heated to 750 K (T_e)	[82]
Zr₇₀Cu₂₉Pd₁	Heated to 593 K (0.91T_o) Annealed at 625 K (0.96T_o) for 120 s	[12] [162]
Hf₅₀Ti₂₅Ni₂₅	Heated to 748 K (0.97T_e)	[163]
Hf₅₉Ni₈Cu₂₀Al₁₀Ti₃	Annealed at 825 K (T_o) for 120 s Annealed at 808 K (0.98T_o) for 360 s	[164]
Hf₆₅Al_7.5Ni₁₀Cu_12.5Pd₅	Annealed at 808 K (0.99T_o) for 360 s	[90–92]
Zr_46.8Ti_8.2Cu_7.5Ni₁₀Be_27.5	Annealed at 648 K (0.92T_o) for 120–9000 s	[93]
Zr_54.5Ti_7.5Cu₂₀Ni₈Al₁₀	Annealed at 698 K (0.96T_o) for 2400 s	[94]
Zr₅₅Cu₂₀Ti₁₅Ni₁₀	Annealed at 652 K (T_o) for 1200 s	[95]
Zr₅₇Cu₂₀Al₁₀Ni₈Ti₅	Annealed at 673 K (0.96T_o) for 2400 s Annealed at 698 K (0.98T_o) for 300 s Annealed at 715 K (1.01T_o) for 60 s	[9] [81] [96]
Zr₅₉Ti₃Cu₂₉Ni₈Al₁₀	Annealed at 703 K (0.98T_o) for 300 s	[96]
Zr₆₀Ni₂₀Al₁₅Pd₅	Annealed at 780 K (T_o) for 120 s	[12]
Zr_64.18Cu_27.5Al_7.5O_0.82	Annealed at 673 K (0.95T_o) for 600–900 s	[97,98]
Zr_64.5Al_7.4Cu_17.4Mo_9.9O_0.8	Annealed at 673 K (0.96T_o) for 1800 s	[99]
Zr_64.5Al_7.4Cu_17.4Ni_9.9O_0.8	Annealed at 673 K (0.93T_o) for 1800 s	[99]
Zr₆₅Al_4.5Cu_27.5Pd₃	Annealed at 705 K (T_o) for 120 s	[12]
Zr₆₅Al_7.5Ni₁₀Cu_12.5Ag₅	Annealed at 693 K (0.96T_o) for 120 min Annealed at 706 K(T_o) for 22–420 s	[79] [100–103]
Zr₆₅Al_7.5Ni₁₀Cu_12.5Au₅	Annealed at 720 K (T_o) for 180 s	[101]
Zr₆₅Al_7.5Ni₁₀Cu_12.5Mo₅	Annealed at 730 K (T_o) for 120 s	[104]
Zr₆₅Al_7.5Ni₁₀Cu_12.5Nb₅	Annealed at 705 K (T_o) for 120 s	[85,92]
Zr₆₅Al_7.5Ni₁₀Cu_12.5Pd₅	Annealed at 705 K (T_o) for 25–180 s	[92,100,101,105]
Zr₆₅Al_7.5Ni₁₀Cu_12.5Pt₅	Annealed at 745 K (T_o) for 180 s	[101]
Zr₆₅Al_7.5Ni₁₀Cu_12.5Ta₅	Annealed at 710 K (T_o) for 60–120 s	[85,92,107]
Zr₆₅Al_7.5Ni₁₀Cu_12.5V₅	Annealed at 700 K (T_o) for 120 s	[85,92]
Zr₆₅Al_7.5Ni₁₀Cu_7.5Ag₁₀	Annealed at 672 K (0.99T_o) for 600–10,800s Annealed at 673 K (0.95T_o) for 3600 s	[109] [108]
Zr₆₅Al_7.5Ni₁₀Cu_7.5Pd₁₀	Annealed at 705 K (T_o) for 60 s	[12,92,101]
Zr₆₅Al_7.5Ni₁₀Pd_17.5	Annealed at 730 K (T_o) for 120 s	[101]
Zr₆₅Cu₁₅Al₁₀Pd₁₀	Annealed at 730 K (0.98T_o) for 3600 s	[111]
Zr₆₅Cu_7.5Al_7.5Ni₁₀Ag₁₀	Annealed at 670 K (0.96T_o) for 7200 s	[52]
Zr_66.7Pd_33.3	Annealed at 750 K (T_o) for 60–300 s	[112]
Zr_69.5Cu₁₂Ni₁₁Al_7.5	Annealed at 693 K (T_o) for 200 s Annealed at 673 K (0.97T_o) for 300 or 700 s	[74] [75]
Zr₇₀Al_7.5Ni₁₀Cu_12.5	Annealed at 710 K (T_o) for 60 s	[105]
Zr₇₀Cu_29.5Au_0.5	Annealed at 635 K (T_o) for 120 s	[12]
Zr₇₀Cu_29.5Pd_0.5	Annealed at 630 K (T_o) for 120 s	[12]
Zr₇₀Ni₂₀Al₉Pd₁	Annealed at 695 K (T_o) for 120 s	[86]
Zr₇₀Pd₂₀Ni₁₀	Annealed at 700 K (1.02T_o) for 120 s	[83]
Zr₇₀Pd₃₀	Annealed at 690 K (0.93T_o) for 120 s Annealed at 740 K (T_o) for 120 s Heated to 727 K (T_p) and cooled	[77,113,114] [84,115,116]
Zr₇₄Al_7.5Ni₁₀Cu_8.5	Annealed at 635 K (T_o) for 120 s	[114]
Zr₈₀Pt₂₀	Annealed at 840 K (T_o) for 120 s	[84,114,115,165]
l-to-l₁/l₂
Cu_47.5Zr₄₀Be_12.5	Annealed at 773 K (T_e) for 10 s	[166]
La_27.5Zr_27.5Al₂₅Cu₁₀Ni₁₀	Cooling the melt	[167]
Ni_58.5Nb_20.25Y_21.25	Cooling the melt	[168]
Pd₃₅Ni₄₅P₂₀	Annealed at 603 K (T_o) for 6 h	[169]
Pd_41.5Ni_41.5P₁₇	Heated to 640 K (T_e)	[117]
Pd₄₁Ni₄₁P₁₈	Heated to 630 K (T_e)	[117,170]
Pd₄₈Ni₃₄P₁₈	Heated to 630 K (T_e)	[171]
Pd₇₄Au₈Si₁₈	Annealed at 665 K (T_o) for 60–600 s	[172]
Pd₇₈Au₆Si₁₆	Annealed at 679 K (T_g) for 180 s	[173]
Ti₂₈Y₂₈Al₂₄Co₂₀	Cooling the melt	[50,174]
Ti₄₅Zr₂₀Be₃₅	Cooling the melt	[175]
Zr₃₃Y₂₇Al₁₅Ni₂₅	Heated to 730 K (T_e)	[176]
l-to-l_1’/l_2’ or short-range ordering
Pd_40.5Ni_40.5P₁₉	Heated to 630 K (T_e) Annealed at 603–673 K (1–1.1T_o) for 1800 s Annealed at 603 K (1.02T_o) for 900–2400 s	[117] [177] [178]
Zr₃₆Ti₂₄Be₄₀	Heated to 663 K (T_p) or Cooling the melt Repetitively heated to 628–683 K (1–1.08T_o)	[179] [175] [180]
Cu₄₆Zr₄₂Al₇Y₅	Heated to 653 K (T_p) for 0.25–8 h Heated to 787 K (T_e)	[181] [180]
Short-range ordering
Pd₄₆Ni₃₆P₁₈	Heating the MGAnnealed at 630 K (T_e) for 60 s	[53,122]
Cu₅₅Zr₄₀Sn₅	Heated to 773 K (T_p) and quenched	[182]
Fe_67.2Dy_5.8B₂₃Nb₄	Heated to 910 K (T_p) and quenched	[183]
Fe_68.2Dy_3.8B_19.2Si_4.8Nb₄	Annealed at 930 K (T_p) for 30 s	[184]
Fe_68.8B_22.9Nb_3.8Y_4.5	Annealed at 922 K (T_p) for 30 s	[185]
Fe₆₈Mo₄Y₆B₂₂	Heated to 913 K (T_p) and quenched	[186]
Fe_69.1Dy_2.9B_19.2Si_4.8Nb₄	Annealed at 930 K (T_p) for 30 s	[184]
Mg₆₀Cu₁₅Ag₁₀Gd₁₀	Heated to 450 K (T_p) and quenched	[180]
Ni₆₁Zr₂₂Nb₇Al₄Ta₅	Heated to 900 K (T_p) and quenched	[180]
Pd₄₆Ni₃₆P₁₈	Annealed at 605 K for 3600 s	[187]
Zr₄₆Ti₂₄Be₄₀	Heated to 691 K (T_e) and quenched	[188]
Glaciation (l₁-to-l₂, l₁-to-g₂ or g₁-to-g₂)
Pd_41.25Ni_41.25P_17.5	Heating the MG	[1]
Pd_42.5Ni_42.5P₁₅	Heating the MG	[2,131]
La_32.5Ce_32.5Co₂₅Al₁₀	Heating the MG	[3]
Nb₂₀Ni₂₀Zr₂₀Ti₂₀Co₂₀	Heating the MG	[4]

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