CSPM EDP Sciences logo
Submit your paper
Search
Menu
All issues Volume 3 / No 6 (2024) Natl Sci Open, 3 6 (2024) 20240047 Full HTML

Table 1

Summary of the effect of pulsed electrocatalysis on different catalytic reactions

Catalyst/ electrode material Applications Method/ Waveform The application of pulsed electrocatalysis Ref.
Roles Objectives
Cu3(DMPz)3 OES PP/Square Surface reconstruction; Rearrangement of surface coverage and pH Improved product selectivity and catalyst stability [48]
Ag OES PC/Square Preventing metal deposition by cathodic reduction Improved product selectivity and catalyst stability [45]
Au/CoOOH Alcohols oxidation PP/Square Modulating the valence of catalysts Improved catalyst stability [74]
Cu OES PP/Square Prevents continuous dissolution of catalyst and deactivation Enhance the yield and long-term stability [70]
Carbon OES PP/Square Mitigating mass transfer limitations; Stabilizing intermediates Improved product yield [22]
Pt Formic acid oxidation PP/Sinusoidal Regulating the desorption/adsorption of intermediate species; Prevents catalyst deactivation Enhance the reaction rate and long-term stability [77]
VxOy-Sn0.9In0.1P2O7 Benzene oxidation PC/Square Steering free radical generation and stabilization Improved product selectivity and FE [67]
Organic reagents OES PC & PP/Square Regulating the generation and reaction of intermediates Improved product selectivity [44]
PdNi Lactic acid oxidation PP/Square Periodic catalyst regeneration Enhance the reaction rate and long-term stability [73]
Cadmium OES PP/Square Mitigating mass transfer limitations; Modulation of the EDL Improved product selectivity; Enhanced the reaction rate [68]
RVC Kolbe reaction PC/Square Regulating the local pH Improved product reaction activity and selectivity [43]
Pt Asymmetric synthesis PP/Square Mitigating mass transfer limitations Improved product selectivity [66]
Pt Alcohols oxidation PP/Triangular Prevents catalyst deactivation Improved product selectivity; Improved catalyst stability [72]
Cu foil CO2RR PP/Square Modulating the valence of catalysts; Regulating the desorption/adsorption of intermediate species Improved product selectivity and FE; Suppressing the HER [124]
Cu(100) CO2RR PP/Square Surface reconstruction Improving the reaction reactivity [24]
Cu2O NCs CO2RR PP/Square Modulating the surface structure and composition of catalysts Steering product selectivity and FE [25]
Cu CO2RR PP/Square Regulating the desorption/adsorption of intermediate species Improved product selectivity and FE [127]
Cu CO2RR PP/Square Modulation of the EDL; Modulating the Catalysts; Regulating the desorption/adsorption of intermediate species Modulation of product selectivity [128]
Cu CO2RR PP/Square Regulating the intermediate species and pH Modulation of product selectivity and reaction rate [123]
Cu CO2RR PP/Square Regulating the local concentration of spices; Modulation the EDL and pH Improved product selectivity and FE [125]
Cu-DHP CO2RR PP/Square Surface reconstruction; Regulating the desorption/adsorption of intermediate species Enhance the product selectivity and long-term stability; Suppressing the HER [61]
Cu CO2RR PP/Square Regulating the local pH and diffusion layer Improved product selectivity and FE [19]
Pt Water splitting PP/Square Mitigating mass transfer limitations Enhance the reaction rate and long-term stability; Reduce energy consumption [46]
Ni Water splitting PP/Square Accelerated bubble diffusion; Modulation of the diffusion layer Enhanced the reaction rate and catalytic efficiency [135]
MnO2 Water splitting PC/Square Mitigating mass transfer limitations; Regulating the diffusion layer Enhance the reaction efficiency [47]
Fe/Fe2+ Cr(Ⅵ) removal PP/Square Mitigating mass transfer limitations; Prevents electrode passivation Reducing energy consumption; Enhanced catalytic efficiency [57]
PbO2 Degradation of malachite green PP/Square Accelerated generation of hydroxyl radicals Reducing energy consumption; Enhanced catalytic efficiency [145]
Nb/BDD Degradation of phenol PC/Square Reducing the side reactions and concentration polarization Reducing energy consumption; Enhanced catalytic efficiency [143]
Functionalized carbon Uranium extraction PC/Square Mitigating mass transfer limitations; Regulating the diffusion of charged ionic High extraction capacity, fast kinetics, and high selectivity [28]
EDTA Heavy metal removal PP/Square Regulating the diffusion and adsorption of charged ionic Enhanced selectivity and efficiency [146]
Cu SAGs NO3RR PP/Square Mitigating mass transfer limitations; Regulating the desorption/adsorption of intermediate species Improved product selectivity and FE; Suppressing the HER [124]
RuIn3/C NO3RR PP/Square Mitigating mass transfer limitations; Regulating the desorption/adsorption of intermediate species Improved product selectivity and FE; Suppressing the HER [49]
LC-Cu NC NO2RR, C-N coupling PP/Square Regulating the diffusion of intermediate species;
Dissolved Cu(II) for catalyst; Adjusting the pH		 Improved product selectivity and FE; Suppressing the side reaction [51]
Fe-TiO2 NRR, NOR PP/Square Regulating the desorption/adsorption of intermediate species; Mitigating mass transfer limitations; Stabilize the catalysts Improved product selectivity and FE; Suppressing the HER and OER [50]
Au NO3RR, C-N coupling PP/Square Mitigating mass transfer limitations; Modulation of the EDL structure; Optimizing the reaction path; Regulating the desorption/adsorption of intermediate species Improved product selectivity and FE [151]
Cu-Ni Tandem NO3RR PP/Square Modulating the valence of catalysts; Regulating the desorption/adsorption of intermediate species Improved product selectivity and FE [149]
PCSs ORR PP/Square Stimulating the cationic effects; Regulating the desorption/adsorption of intermediate species; Improved product selectivity and FE [53]
Biomass-derived carbon ORR PP/Square Stabilize the catalysts; Regulating the desorption/adsorption of intermediate species; Optimizing the reaction path Improved product selectivity, FE, and catalyst stability [54]
Graphite felt ORR PP/Square Modulation of the EDL; Regulating the desorption/adsorption of intermediate species Improved product selectivity and FE [55]

Notes: OES, organic electrocatalytic synthesis; PP, pulsed potential; PC, pulsed current.

Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.

Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.

Initial download of the metrics may take a while.